TY - JOUR
T1 - Synthesis and reactivities of enantiomerically pure β hydroxyalkyl and β-aminoalkyl ferrocenyl sulfides
AU - Bernardi, Luca
AU - Bonini, Bianca F.
AU - Comes-Franchini, Mauro
AU - Fochi, Mariafrancesca
AU - Mazzanti, Germana
AU - Ricci, Alfredo
AU - Varchi, Greta
PY - 2002/8
Y1 - 2002/8
N2 - Enantiomerically pure β-hydroxyalkyl and β-aminoalkyl ferrocenyl sulfides have been synthesized in good yields from mercaptoferrocene and amino alcohol derivatives. Primary β-aminoalkyl sulfides allowed the synthesis of tetrahydro-1,4-thiazepines containing the ferrocene moiety with good diastereoselectivity and β-iminoalkyl sulfides. Some of these derivatives have successfully been employed as ligands for palladium-catalyzed allylic substitution, with asymmetric induction of up to 99% ee. (
AB - Enantiomerically pure β-hydroxyalkyl and β-aminoalkyl ferrocenyl sulfides have been synthesized in good yields from mercaptoferrocene and amino alcohol derivatives. Primary β-aminoalkyl sulfides allowed the synthesis of tetrahydro-1,4-thiazepines containing the ferrocene moiety with good diastereoselectivity and β-iminoalkyl sulfides. Some of these derivatives have successfully been employed as ligands for palladium-catalyzed allylic substitution, with asymmetric induction of up to 99% ee. (
KW - Allylic substitution
KW - Catalysis
KW - Ferrocene
KW - Palladium
KW - Sandwich complexes
KW - Sulfur
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U2 - 10.1002/1099-0690(200208)2002:16<2776::AID-EJOC2776>3.0.CO;2-Y
DO - 10.1002/1099-0690(200208)2002:16<2776::AID-EJOC2776>3.0.CO;2-Y
M3 - Article
AN - SCOPUS:0036677495
SN - 1434-193X
SP - 2776
EP - 2784
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
IS - 16
ER -