Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks

Lei Mei; Lin Wang; Li Yong Yuan; Shu Wen An; Yu Liang Zhao; Zhi Fang Chai; Peter C. Burns; Wei Qun Shi

doi:10.1039/c5cc04409j

Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks

Lei Mei, Lin Wang, Li Yong Yuan, Shu Wen An, Yu Liang Zhao, Zhi Fang Chai, Peter C. Burns, Wei Qun Shi

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

The assembly of two-dimensional (2D) large channel uranyl-organic polyrotaxane networks as well as structural regulation of uranyl-bearing units using jointed cucurbit[6]uril-based pseudorotaxanes with integral rigidity based on supramolecular inclusion is presented for the first time. This construction strategy concerning controlling molecular integral rigidity based on supramolecular inclusion may afford an entirely new methodology for coordination chemistry.

Original language	English (US)
Pages (from-to)	11990-11993
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	60
DOIs	https://doi.org/10.1039/c5cc04409j
State	Published - Aug 4 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The assembly of two-dimensional (2D) large channel uranyl-organic polyrotaxane networks as well as structural regulation of uranyl-bearing units using jointed cucurbit[6]uril-based pseudorotaxanes with integral rigidity based on supramolecular inclusion is presented for the first time. This construction strategy concerning controlling molecular integral rigidity based on supramolecular inclusion may afford an entirely new methodology for coordination chemistry.",

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AU - Mei, Lei

AU - Wang, Lin

AU - Yuan, Li Yong

AU - An, Shu Wen

AU - Zhao, Yu Liang

AU - Chai, Zhi Fang

AU - Burns, Peter C.

AU - Shi, Wei Qun

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AB - The assembly of two-dimensional (2D) large channel uranyl-organic polyrotaxane networks as well as structural regulation of uranyl-bearing units using jointed cucurbit[6]uril-based pseudorotaxanes with integral rigidity based on supramolecular inclusion is presented for the first time. This construction strategy concerning controlling molecular integral rigidity based on supramolecular inclusion may afford an entirely new methodology for coordination chemistry.

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Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks

Abstract

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