Study of multihydroxylated processes of Gd@C82 by ICP-MASS

Yue Cheng; Kaiming Liu; Gengmei Xing; Hui Yuan; Long Jing; Yuliang Zhao

doi:10.1007/s10967-007-0619-x

Study of multihydroxylated processes of Gd@C₈₂ by ICP-MASS

Yue Cheng, Kaiming Liu, Gengmei Xing, Hui Yuan, Long Jing, Yuliang Zhao

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The water-solubilization of metallofullerenes is important for their potential applications, but their formation processes are still not clear, and the formation yield is uncontrollable. In this paper, we quantitatively studied the water-solubilizing process of Gd@C₈₂ with hydroxylation reaction using ICP-MASS techniques. For the first time, it was found that the formation yield of the multihydroxylated Gd@C₈₂ is declined quickly with the break up of carbon cage of Gd@C₈₂ in the hydroxylated processes. The observation revealed a way to control the hydroxylation processes and increase the formation yield.

Original language	English (US)
Pages (from-to)	537-540
Number of pages	4
Journal	Journal of Radioanalytical and Nuclear Chemistry
Volume	272
Issue number	3
DOIs	https://doi.org/10.1007/s10967-007-0619-x
State	Published - Jun 2007

ASJC Scopus subject areas

Analytical Chemistry
Nuclear Energy and Engineering
Radiology Nuclear Medicine and imaging
Pollution
Spectroscopy
Public Health, Environmental and Occupational Health
Health, Toxicology and Mutagenesis

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abstract = "The water-solubilization of metallofullerenes is important for their potential applications, but their formation processes are still not clear, and the formation yield is uncontrollable. In this paper, we quantitatively studied the water-solubilizing process of Gd@C82 with hydroxylation reaction using ICP-MASS techniques. For the first time, it was found that the formation yield of the multihydroxylated Gd@C82 is declined quickly with the break up of carbon cage of Gd@C82 in the hydroxylated processes. The observation revealed a way to control the hydroxylation processes and increase the formation yield.",

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AU - Cheng, Yue

AU - Liu, Kaiming

AU - Xing, Gengmei

AU - Yuan, Hui

AU - Jing, Long

AU - Zhao, Yuliang

PY - 2007/6

Y1 - 2007/6

N2 - The water-solubilization of metallofullerenes is important for their potential applications, but their formation processes are still not clear, and the formation yield is uncontrollable. In this paper, we quantitatively studied the water-solubilizing process of Gd@C82 with hydroxylation reaction using ICP-MASS techniques. For the first time, it was found that the formation yield of the multihydroxylated Gd@C82 is declined quickly with the break up of carbon cage of Gd@C82 in the hydroxylated processes. The observation revealed a way to control the hydroxylation processes and increase the formation yield.

AB - The water-solubilization of metallofullerenes is important for their potential applications, but their formation processes are still not clear, and the formation yield is uncontrollable. In this paper, we quantitatively studied the water-solubilizing process of Gd@C82 with hydroxylation reaction using ICP-MASS techniques. For the first time, it was found that the formation yield of the multihydroxylated Gd@C82 is declined quickly with the break up of carbon cage of Gd@C82 in the hydroxylated processes. The observation revealed a way to control the hydroxylation processes and increase the formation yield.

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ER -

Study of multihydroxylated processes of Gd@C₈₂ by ICP-MASS

Abstract

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