TY - JOUR
T1 - Scaling properties and local forms of the correlation-energy functional
AU - Pino, Ramiro
AU - López-Boada, Roberto
N1 - Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.
PY - 1997
Y1 - 1997
N2 - The scaling properties of the exact correlation-energy functional are applied in the study of the general rational, polynomial, and logarithmic local forms (and their combinations) of the correlation-energy functional, which depend on the density. It is concluded that these forms cannot satisfy the uniform and nonuniform scaling properties at the same time; therefore, they would have to be modified to represent exact forms of the correlation-energy density functional, at least in the high- and low-density limits. These results are not affected by the application of the local spin density or the self-interaction correction procedures to the above functionals.
AB - The scaling properties of the exact correlation-energy functional are applied in the study of the general rational, polynomial, and logarithmic local forms (and their combinations) of the correlation-energy functional, which depend on the density. It is concluded that these forms cannot satisfy the uniform and nonuniform scaling properties at the same time; therefore, they would have to be modified to represent exact forms of the correlation-energy density functional, at least in the high- and low-density limits. These results are not affected by the application of the local spin density or the self-interaction correction procedures to the above functionals.
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U2 - 10.1103/PhysRevA.56.5169
DO - 10.1103/PhysRevA.56.5169
M3 - Article
AN - SCOPUS:0041337414
SN - 1050-2947
VL - 56
SP - 5169
EP - 5172
JO - Physical Review A - Atomic, Molecular, and Optical Physics
JF - Physical Review A - Atomic, Molecular, and Optical Physics
IS - 6
ER -