Phenoxo-bridged symmetrical homobinuclear complexes derived from an "end-off" compartmental ligand, 2,6-bis[5′-chloro-3′-phenyl-1H-indole-2′-carboxamidyliminomethyl]-4-methylphenol

Fazlur Rahaman, Omkar B. Ijare, Y. Jadegoud, B. H.M. Mruthyunjayaswamy

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

A compartment ligand 2,6-bis[5′-chloro-3′-phenyl-1H-indole-2′-carboxamidyliminomethyl]-4-methylphenol was prepared and homobinuclear phenol-bridged Cu(II), Ni(II), Co(II), Zn(II), Cd(II), Hg(II), Fe(III), and Mn(II) complexes have been prepared by the template method using the precursors 2,6-diformyl-4-methylphenol, 5-chloro-3-phenylindole-2-carbohy-drazide and metal chlorides in 1:2:2 ratio, respectively. The complexes were characterized by elemental analyses, conductivity measurements, magnetic susceptibility data, IR, NMR, FAB mass and ESR spectra, TGA, and powder XRD data. Cu(II), Co(II), Zn(II), Cd(II) and Hg(II) complexes exhibit square pyramidal geometry whereas Ni(II), Mn(II), and Fe(III) complexes are octahedral. Low magnetic moment values for Cu(II), Ni(II), Co(II), Fe(III), and Mn(II) complexes show antiferromagnetic spin-exchange interaction between two metal centers in binuclear complexes. The ligand and its complexes were tested for antibacterial activity against Escherichia coli and Staphyloccocus aureus, and antifungal activity against Aspergillus niger and Candida albicans.

Original languageEnglish (US)
Pages (from-to)1457-1467
Number of pages11
JournalJournal of Coordination Chemistry
Volume62
Issue number9
DOIs
StatePublished - May 2009

Keywords

  • "End-off" compartmental ligand
  • Binuclear complexes
  • Phenoxo-bridged complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Phenoxo-bridged symmetrical homobinuclear complexes derived from an "end-off" compartmental ligand, 2,6-bis[5′-chloro-3′-phenyl-1H-indole-2′-carboxamidyliminomethyl]-4-methylphenol'. Together they form a unique fingerprint.

Cite this