Origin of the anomalous phosphorescence of aromatic ketones. Xanthone in 3-methylpentane

Henry J. Pownall; Robert E. Connors; J. Robert Huberm

doi:10.1016/0009-2614(73)80578-0

Origin of the anomalous phosphorescence of aromatic ketones. Xanthone in 3-methylpentane

Henry J. Pownall, Robert E. Connors, J. Robert Huberm

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Abstract

Based on an emission study of xanthone at ≈2 and 77°K it is concluded that the "dual" phosphorescence at 77°K in a 3-methylpentane glass matrix is due to emission from two n,π^* triplet states of xanthone. The two triplet states and their respective ground states are distinguished by their different molecular geometries.

Original language	English (US)
Pages (from-to)	403-405
Number of pages	3
Journal	Chemical Physics Letters
Volume	22
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(73)80578-0
State	Published - Oct 1 1973

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General Physics and Astronomy
Physical and Theoretical Chemistry

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Endocrinology, Diabetes and Metabolism

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title = "Origin of the anomalous phosphorescence of aromatic ketones. Xanthone in 3-methylpentane",

abstract = "Based on an emission study of xanthone at ≈2 and 77°K it is concluded that the {"}dual{"} phosphorescence at 77°K in a 3-methylpentane glass matrix is due to emission from two n,π* triplet states of xanthone. The two triplet states and their respective ground states are distinguished by their different molecular geometries.",

author = "Pownall, \{Henry J.\} and Connors, \{Robert E.\} and \{Robert Huberm\}, J.",

note = "Funding Information: This work was partially supported by a Petroleum Research Fund administred by the American Chemical Society (R.E.C.) and by a grant from the Damon Runyon Foundation, DRG 1162 (H.J.P.). Copyright: Copyright 2014 Elsevier B.V., All rights reserved.",

year = "1973",

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doi = "10.1016/0009-2614(73)80578-0",

language = "English (US)",

volume = "22",

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T1 - Origin of the anomalous phosphorescence of aromatic ketones. Xanthone in 3-methylpentane

AU - Pownall, Henry J.

AU - Connors, Robert E.

AU - Robert Huberm, J.

N1 - Funding Information: This work was partially supported by a Petroleum Research Fund administred by the American Chemical Society (R.E.C.) and by a grant from the Damon Runyon Foundation, DRG 1162 (H.J.P.). Copyright: Copyright 2014 Elsevier B.V., All rights reserved.

PY - 1973/10/1

Y1 - 1973/10/1

N2 - Based on an emission study of xanthone at ≈2 and 77°K it is concluded that the "dual" phosphorescence at 77°K in a 3-methylpentane glass matrix is due to emission from two n,π* triplet states of xanthone. The two triplet states and their respective ground states are distinguished by their different molecular geometries.

AB - Based on an emission study of xanthone at ≈2 and 77°K it is concluded that the "dual" phosphorescence at 77°K in a 3-methylpentane glass matrix is due to emission from two n,π* triplet states of xanthone. The two triplet states and their respective ground states are distinguished by their different molecular geometries.

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U2 - 10.1016/0009-2614(73)80578-0

DO - 10.1016/0009-2614(73)80578-0

M3 - Article

AN - SCOPUS:4243892718

SN - 0009-2614

VL - 22

SP - 403

EP - 405

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Origin of the anomalous phosphorescence of aromatic ketones. Xanthone in 3-methylpentane

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