New ligands that promote cross-coupling reactions between aryl halides and unactivated arenes

Yatao Qiu; Yanghan Liu; Kai Yang; Wenkun Hong; Zheng Li; Zhaoyang Wang; Zhiyi Yao; Sheng Jiang

doi:10.1021/ol2009208

New ligands that promote cross-coupling reactions between aryl halides and unactivated arenes

Yatao Qiu, Yanghan Liu, Kai Yang, Wenkun Hong, Zheng Li, Zhaoyang Wang, Zhiyi Yao, Sheng Jiang

Research output: Contribution to journal › Article › peer-review

133 Scopus citations

Abstract

Several ligands were designed to promote transition-metal-free cross-coupling reactions of aryl halides with benzene derivatives. Among the systems probed, quinoline-1-amino-2-carboxylic acid was found to serve as an excellent catalyst for cross-coupling between aryl halides and unactivated benzene. Reactions using this inexpensive catalytic system displayed a high functional group tolerance as well as excellent chemoselectivities.

Original language	English (US)
Pages (from-to)	3556-3559
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	14
DOIs	https://doi.org/10.1021/ol2009208
State	Published - Jul 15 2011

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol2009208

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abstract = "Several ligands were designed to promote transition-metal-free cross-coupling reactions of aryl halides with benzene derivatives. Among the systems probed, quinoline-1-amino-2-carboxylic acid was found to serve as an excellent catalyst for cross-coupling between aryl halides and unactivated benzene. Reactions using this inexpensive catalytic system displayed a high functional group tolerance as well as excellent chemoselectivities.",

author = "Yatao Qiu and Yanghan Liu and Kai Yang and Wenkun Hong and Zheng Li and Zhaoyang Wang and Zhiyi Yao and Sheng Jiang",

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T1 - New ligands that promote cross-coupling reactions between aryl halides and unactivated arenes

AU - Qiu, Yatao

AU - Liu, Yanghan

AU - Yang, Kai

AU - Hong, Wenkun

AU - Li, Zheng

AU - Wang, Zhaoyang

AU - Yao, Zhiyi

AU - Jiang, Sheng

PY - 2011/7/15

Y1 - 2011/7/15

N2 - Several ligands were designed to promote transition-metal-free cross-coupling reactions of aryl halides with benzene derivatives. Among the systems probed, quinoline-1-amino-2-carboxylic acid was found to serve as an excellent catalyst for cross-coupling between aryl halides and unactivated benzene. Reactions using this inexpensive catalytic system displayed a high functional group tolerance as well as excellent chemoselectivities.

AB - Several ligands were designed to promote transition-metal-free cross-coupling reactions of aryl halides with benzene derivatives. Among the systems probed, quinoline-1-amino-2-carboxylic acid was found to serve as an excellent catalyst for cross-coupling between aryl halides and unactivated benzene. Reactions using this inexpensive catalytic system displayed a high functional group tolerance as well as excellent chemoselectivities.

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JF - Organic Letters

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ER -

New ligands that promote cross-coupling reactions between aryl halides and unactivated arenes

Abstract

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