New chiral allylaminosilanes and their use in asymmetric Sakurai reactions

B. F. Bonini; M. Comes-Franchini; M. Fochi; G. Mazzanti; A. Ricci; G. Varchi

doi:10.1016/S0957-4166(98)00327-9

New chiral allylaminosilanes and their use in asymmetric Sakurai reactions

B. F. Bonini, M. Comes-Franchini, M. Fochi, G. Mazzanti, A. Ricci, G. Varchi

Houston Methodist

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl₄ to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30%.

Original language	English (US)
Pages (from-to)	2979-2981
Number of pages	3
Journal	Tetrahedron Asymmetry
Volume	9
Issue number	17
DOIs	https://doi.org/10.1016/S0957-4166(98)00327-9
State	Published - Sep 4 1998

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "New chiral allylaminosilanes and their use in asymmetric Sakurai reactions",

abstract = "The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl4 to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30\%.",

author = "Bonini, \{B. F.\} and M. Comes-Franchini and M. Fochi and G. Mazzanti and A. Ricci and G. Varchi",

note = "Funding Information: This work was supported by Progetto Strategico, Tecnologie Chimiche Innovative (CNR, Italy) and by University of Bologna (`Funds For Selected Research Topics, 1996–1998'). Copyright: Copyright 2004 Elsevier Science B.V., Amsterdam. All rights reserved.",

year = "1998",

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doi = "10.1016/S0957-4166(98)00327-9",

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T1 - New chiral allylaminosilanes and their use in asymmetric Sakurai reactions

AU - Bonini, B. F.

AU - Comes-Franchini, M.

AU - Fochi, M.

AU - Mazzanti, G.

AU - Ricci, A.

AU - Varchi, G.

N1 - Funding Information: This work was supported by Progetto Strategico, Tecnologie Chimiche Innovative (CNR, Italy) and by University of Bologna (`Funds For Selected Research Topics, 1996–1998'). Copyright: Copyright 2004 Elsevier Science B.V., Amsterdam. All rights reserved.

PY - 1998/9/4

Y1 - 1998/9/4

N2 - The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl4 to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30%.

AB - The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl4 to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30%.

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U2 - 10.1016/S0957-4166(98)00327-9

DO - 10.1016/S0957-4166(98)00327-9

M3 - Article

AN - SCOPUS:0032483449

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VL - 9

SP - 2979

EP - 2981

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 17

ER -

New chiral allylaminosilanes and their use in asymmetric Sakurai reactions

Abstract

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