New chiral allylaminosilanes and their use in asymmetric Sakurai reactions

B. F. Bonini, M. Comes-Franchini, M. Fochi, G. Mazzanti, A. Ricci, G. Varchi

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl4 to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30%.

Original languageEnglish (US)
Pages (from-to)2979-2981
Number of pages3
JournalTetrahedron Asymmetry
Volume9
Issue number17
DOIs
StatePublished - Sep 4 1998

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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