MoS₂-Nanosheet-Assisted Coordination of Metal Ions with Porphyrin for Rapid Detection and Removal of Cadmium Ions in Aqueous Media

Molybdenum disulfide (MoS₂) is a two-dimensional (2D) graphene-like material that is gaining great attention because of its potential application in various fields. Here, we reported a self-assembled nanocomposite consisted of MoS₂ nanosheets and 5,10,15,20-tetrakis(1-methyl-4-pyridinio)porphyrintetra(p-toluenesulfonate) (TMPyP), named MoS₂@TMPyP. This nanocomposite can be used as a sensing probe for low cost, rapid, selective detection of cadmium (Cd²⁺) ions. It is found that a new Soret band at 442 nm in UV-vis absorption spectra represented the coordination of Cd²⁺ ions into TMPyP of the MoS₂@TMPyP. The coordination rates between TMPyP and Cd²⁺ ions is greatly accelerated from 72 h to 20 min with the assistance of MoS₂, which is 200 times faster than in the absence of MoS₂. The limit of detection (LOD) of the Cd²⁺ is as low as 7.2 × 10^-8 mol/L. The binding behavior between the cationic TMPyP and MoS₂ nanosheets was corroborated by molecular dynamics simulation and various control experiments. The results demonstrated that electrostatic interaction was the main force for driving TMPyP enriching around the MoS₂ surface, resulting in an accelerated complexation of Cd²⁺ and TMPyP. Moreover, MoS₂@TMPyP nanocomposite can also be used for removing of Cd²⁺ in water. The removal efficiency (RF) of the MoS₂@TMPyP can reach to 91% for high concentrations of Cd²⁺. This work provides a new insight into detection and removal of Cd²⁺ ions in water.