High selectivity towards small copper ions by a preorganized phenanthroline-derived tetradentate ligand and new insight into the complexation mechanism

Cheng Liang Xiao; Qun Yan Wu; Lei Mei; Li Yong Yuan; Cong Zhi Wang; Yu Liang Zhao; Zhi Fang Chai; Wei Qun Shi

doi:10.1039/c4dt01489h

High selectivity towards small copper ions by a preorganized phenanthroline-derived tetradentate ligand and new insight into the complexation mechanism

Cheng Liang Xiao, Qun Yan Wu, Lei Mei, Li Yong Yuan, Cong Zhi Wang, Yu Liang Zhao, Zhi Fang Chai, Wei Qun Shi

Houston Methodist

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A preorganized tetradentate phenanthroline-derived amide ligand, N,N′-diethyl-N,N′-ditolyl-2,9-dicarboxamide-1,10-phenanthroline (Et-Tol-DAPhen), was found to show high selectivity towards small copper ions, which might be due to the change of the coordination mechanism from tetradentate to terdentate mode. This journal is

Original language	English (US)
Pages (from-to)	12470-12473
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	33
DOIs	https://doi.org/10.1039/c4dt01489h
State	Published - Sep 7 2014

ASJC Scopus subject areas

Inorganic Chemistry

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title = "High selectivity towards small copper ions by a preorganized phenanthroline-derived tetradentate ligand and new insight into the complexation mechanism",

abstract = "A preorganized tetradentate phenanthroline-derived amide ligand, N,N′-diethyl-N,N′-ditolyl-2,9-dicarboxamide-1,10-phenanthroline (Et-Tol-DAPhen), was found to show high selectivity towards small copper ions, which might be due to the change of the coordination mechanism from tetradentate to terdentate mode. This journal is",

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doi = "10.1039/c4dt01489h",

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T1 - High selectivity towards small copper ions by a preorganized phenanthroline-derived tetradentate ligand and new insight into the complexation mechanism

AU - Xiao, Cheng Liang

AU - Wu, Qun Yan

AU - Mei, Lei

AU - Yuan, Li Yong

AU - Wang, Cong Zhi

AU - Zhao, Yu Liang

AU - Chai, Zhi Fang

AU - Shi, Wei Qun

PY - 2014/9/7

Y1 - 2014/9/7

N2 - A preorganized tetradentate phenanthroline-derived amide ligand, N,N′-diethyl-N,N′-ditolyl-2,9-dicarboxamide-1,10-phenanthroline (Et-Tol-DAPhen), was found to show high selectivity towards small copper ions, which might be due to the change of the coordination mechanism from tetradentate to terdentate mode. This journal is

AB - A preorganized tetradentate phenanthroline-derived amide ligand, N,N′-diethyl-N,N′-ditolyl-2,9-dicarboxamide-1,10-phenanthroline (Et-Tol-DAPhen), was found to show high selectivity towards small copper ions, which might be due to the change of the coordination mechanism from tetradentate to terdentate mode. This journal is

UR - https://www.scopus.com/pages/publications/84904990653

UR - https://www.scopus.com/inward/citedby.url?scp=84904990653&partnerID=8YFLogxK

U2 - 10.1039/c4dt01489h

DO - 10.1039/c4dt01489h

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SN - 1477-9226

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EP - 12473

JO - Dalton Transactions

JF - Dalton Transactions

IS - 33

ER -

High selectivity towards small copper ions by a preorganized phenanthroline-derived tetradentate ligand and new insight into the complexation mechanism

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