TY - JOUR
T1 - First endohedral metallofullerene-containing polymer
T2 - Preparation and characterization of Gd@C82-polystyrene
AU - Yue, Dongmei
AU - Bai, Xiaojuan
AU - Zhao, Shixiong
AU - Miao, Xiaopei
AU - Li, Meixian
AU - Dong, Jinquan
AU - Ibrahim, Kurash
AU - Wang, Jiaou
AU - Zhao, Yuliang
AU - Yuan, Hui
AU - Xing, Gengmei
AU - Sun, Baoyun
PY - 2010/5/6
Y1 - 2010/5/6
N2 - Metallofullerene-containing copolymers (0.12, 0.20, 0.40, and 0.60 wt % Gd@C82) were first synthesized via radical bulk copolymerization. The structures and the properties of the new polymers, Gd@C82-PS, were investigated by GPC, UV-vis spectroscopy, FTIR, 13C NMR, CV/DPV, and XPS. The polymerization behavior of the metallofullerene and the properties of the Gd@C82-PS polymers were different from those of C60-PS and PS. Gd@C82 exhibited a stronger radical-scavenging ability than that of hollow fullerenes in the polymerization. Molecular weights and the electron-accepting ability of the polymers were discussed and possible mechanisms of the influences were proposed.
AB - Metallofullerene-containing copolymers (0.12, 0.20, 0.40, and 0.60 wt % Gd@C82) were first synthesized via radical bulk copolymerization. The structures and the properties of the new polymers, Gd@C82-PS, were investigated by GPC, UV-vis spectroscopy, FTIR, 13C NMR, CV/DPV, and XPS. The polymerization behavior of the metallofullerene and the properties of the Gd@C82-PS polymers were different from those of C60-PS and PS. Gd@C82 exhibited a stronger radical-scavenging ability than that of hollow fullerenes in the polymerization. Molecular weights and the electron-accepting ability of the polymers were discussed and possible mechanisms of the influences were proposed.
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U2 - 10.1021/jp9114578
DO - 10.1021/jp9114578
M3 - Article
AN - SCOPUS:77951905975
VL - 114
SP - 7631
EP - 7636
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 17
ER -