Europium, uranyl, and thorium-phenanthroline amide complexes in acetonitrile solution: An ESI-MS and DFT combined investigation

Cheng Liang Xiao, Cong Zhi Wang, Lei Mei, Xin Rui Zhang, Nathalie Wall, Yu Liang Zhao, Zhi Fang Chai, Wei Qun Shi

Research output: Contribution to journalArticle

44 Scopus citations

Abstract

The tetradentate N,N′-diethyl-N,N′-ditolyl-2,9-diamide-1,10-phenanthroline (Et-Tol-DAPhen) ligand with hard-soft donor atoms has been demonstrated to be promising for the group separation of actinides from highly acidic nuclear wastes. To identify the formed complexes of this ligand with actinides and lanthanides, electrospray ionization mass spectrometry (ESI-MS) combined with density functional theory (DFT) calculations was used to probe the possible complexation processes. The 1:2 Eu-L species ([EuL2(NO3)]2+) can be observed in ESI-MS at low metal-to-ligand ([M]/[L]) ratios, whereas the 1:1 Eu-L species ([EuL(NO3)2]+) can be observed when the [M]/[L] ratio is higher than 1.0. However, ([UO2L(NO3)]+) is the only detected species for the uranyl complexes. The [ThL2(NO3)2]2+ species can be observed at low [M]/[L] ratios; the 1:2 species ([ThL2(NO3)]3+) and a new 1:1 species ([ThL(NO3)3]+) can be detected at high [M]/[L] ratios. Collision-induced dissociation (CID) results showed that Et-Tol-DAPhen ligands can coordinate strongly with metal ions, and the coordination moieties remain intact under CID conditions. Natural bond orbital (NBO), molecular electrostatic potential (MEP), electron localization function (ELF), atoms in molecules (AIM) and molecular orbital (MO) analyses indicated that the metal-ligand bonds of the actinide complexes exhibited more covalent character than those of the lanthanide complexes. In addition, according to thermodynamic analysis, the stable cationic M-L complexes in acetonitrile are found to be in good agreement with the ESI-MS results.

Original languageEnglish (US)
Pages (from-to)14376-14387
Number of pages12
JournalDalton Transactions
Volume44
Issue number32
DOIs
StatePublished - Aug 28 2015

ASJC Scopus subject areas

  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Europium, uranyl, and thorium-phenanthroline amide complexes in acetonitrile solution: An ESI-MS and DFT combined investigation'. Together they form a unique fingerprint.

Cite this