Determination of the anomeric configuration in carbohydrates by longitudinal cross-correlated relaxation studies: Application to mono- And disaccharides

Kumar Pichumani, Xiang Zou, Tilak Chandra, Kenneth L. Brown

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

The role of cross-correlated relaxation between the anomeric proton chemical shift anisotropy (CSA) and its dipolar relaxation with nearby proton on the longitudinal relaxation in mono- and disaccharides at two magnetic field strengths has been investigated and shown to directly report the identity of their anomeric configuration.

Original languageEnglish (US)
Pages (from-to)734-738
Number of pages5
JournalMagnetic Resonance in Chemistry
Volume45
Issue number9
DOIs
StatePublished - Sep 1 2007

Keywords

  • Anomeric configuration
  • Chemical shift anisotropy
  • Cross-correlated relaxation
  • Mono- And disaccharides

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)

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