Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with the: Para -C-H of unprotected aniline

Qian Xu; Gang Yu; Min Liu; Chang Peng; M. Katherine Banks; Weijian Xu; Ruoxi Wu; Yanbing Lu

doi:10.1039/c8cy01423j

Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with the: Para -C-H of unprotected aniline

Qian Xu, Gang Yu, Min Liu, Chang Peng, M. Katherine Banks, Weijian Xu, Ruoxi Wu, Yanbing Lu

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

This paper presents a novel method for synthesizing para-aminobenzophenone and its derivatives (p-ABPs) using a coumarin-surfactant modified polyoxometalate as the catalyst. Preliminary mechanistic studies indicate that the reaction has undergone an oxidative cross dehydrogenative coupling process. This method has the advantages of an easy process, a convenient raw material source, safe and green oxidants, and tolerances of several functional groups.

Original language	English (US)
Pages (from-to)	5133-5136
Number of pages	4
Journal	Catalysis Science and Technology
Volume	8
Issue number	20
DOIs	https://doi.org/10.1039/c8cy01423j
State	Published - 2018

ASJC Scopus subject areas

Catalysis

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title = "Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with the: Para -C-H of unprotected aniline",

abstract = "This paper presents a novel method for synthesizing para-aminobenzophenone and its derivatives (p-ABPs) using a coumarin-surfactant modified polyoxometalate as the catalyst. Preliminary mechanistic studies indicate that the reaction has undergone an oxidative cross dehydrogenative coupling process. This method has the advantages of an easy process, a convenient raw material source, safe and green oxidants, and tolerances of several functional groups.",

author = "Qian Xu and Gang Yu and Min Liu and Chang Peng and Banks, {M. Katherine} and Weijian Xu and Ruoxi Wu and Yanbing Lu",

note = "Funding Information: The authors acknowledge the financial support from the Qatar National Research Fund, Grant Number NPRP8-1292-2-548. Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",

year = "2018",

doi = "10.1039/c8cy01423j",

language = "English (US)",

volume = "8",

pages = "5133--5136",

journal = "Catalysis Science and Technology",

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T1 - Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with the

T2 - Para -C-H of unprotected aniline

AU - Xu, Qian

AU - Yu, Gang

AU - Liu, Min

AU - Peng, Chang

AU - Banks, M. Katherine

AU - Xu, Weijian

AU - Wu, Ruoxi

AU - Lu, Yanbing

N1 - Funding Information: The authors acknowledge the financial support from the Qatar National Research Fund, Grant Number NPRP8-1292-2-548. Publisher Copyright: © 2018 The Royal Society of Chemistry. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 2018

Y1 - 2018

N2 - This paper presents a novel method for synthesizing para-aminobenzophenone and its derivatives (p-ABPs) using a coumarin-surfactant modified polyoxometalate as the catalyst. Preliminary mechanistic studies indicate that the reaction has undergone an oxidative cross dehydrogenative coupling process. This method has the advantages of an easy process, a convenient raw material source, safe and green oxidants, and tolerances of several functional groups.

AB - This paper presents a novel method for synthesizing para-aminobenzophenone and its derivatives (p-ABPs) using a coumarin-surfactant modified polyoxometalate as the catalyst. Preliminary mechanistic studies indicate that the reaction has undergone an oxidative cross dehydrogenative coupling process. This method has the advantages of an easy process, a convenient raw material source, safe and green oxidants, and tolerances of several functional groups.

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Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with the: Para -C-H of unprotected aniline

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