Coumarin-surfactant modified polyoxometalate as highly efficient catalysts for the selective oxidation of benzyl alcohol with air

Qian Xu; Shuyi Li; M. Katherine Banks; Weijian Xu; Ruoxi Wu

doi:10.1016/j.catcom.2018.05.006

Coumarin-surfactant modified polyoxometalate as highly efficient catalysts for the selective oxidation of benzyl alcohol with air

Qian Xu, Shuyi Li, M. Katherine Banks, Weijian Xu, Ruoxi Wu

Research output: Contribution to journal › Article

4 Scopus citations

Abstract

Two novel polyoxometalate-based catalysts were prepared by modifying Keggin POM H₄PMo₁₁VO₄₀ with a coumarin-surfactant through electrostatic interactions. The results indicate that (Coumarin)₃HPMo₁₁VO₄₀ exhibits excellent catalytic activity in the selective oxidation of benzyl alcohol using air as the oxidant, where the conversion of benzyl alcohol is 99%, and the selectivity for benzaldehyde is 100%. The excellent catalytic performance can be attributed to π-π* conjugate effects with the reactant, and the structural characteristics of the large BET specific surface area and pore size of the catalyst.

Original language	English (US)
Pages (from-to)	24-27
Number of pages	4
Journal	Catalysis Communications
Volume	114
DOIs	https://doi.org/10.1016/j.catcom.2018.05.006
State	Published - Aug 2018

Keywords

Benzaldehyde (BzH)
Benzyl alcohol (BzOH)
Coumarin-surfactant
Polyoxometalate (POM)

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Process Chemistry and Technology

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@article{30c32ea995d2406b977f1160f115d173,

title = "Coumarin-surfactant modified polyoxometalate as highly efficient catalysts for the selective oxidation of benzyl alcohol with air",

abstract = "Two novel polyoxometalate-based catalysts were prepared by modifying Keggin POM H4PMo11VO40 with a coumarin-surfactant through electrostatic interactions. The results indicate that (Coumarin)3HPMo11VO40 exhibits excellent catalytic activity in the selective oxidation of benzyl alcohol using air as the oxidant, where the conversion of benzyl alcohol is 99%, and the selectivity for benzaldehyde is 100%. The excellent catalytic performance can be attributed to π-π* conjugate effects with the reactant, and the structural characteristics of the large BET specific surface area and pore size of the catalyst.",

keywords = "Benzaldehyde (BzH), Benzyl alcohol (BzOH), Coumarin-surfactant, Polyoxometalate (POM)",

author = "Qian Xu and Shuyi Li and {Katherine Banks}, M. and Weijian Xu and Ruoxi Wu",

year = "2018",

month = aug,

doi = "10.1016/j.catcom.2018.05.006",

language = "English (US)",

volume = "114",

pages = "24--27",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier",

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T1 - Coumarin-surfactant modified polyoxometalate as highly efficient catalysts for the selective oxidation of benzyl alcohol with air

AU - Xu, Qian

AU - Li, Shuyi

AU - Katherine Banks, M.

AU - Xu, Weijian

AU - Wu, Ruoxi

PY - 2018/8

Y1 - 2018/8

N2 - Two novel polyoxometalate-based catalysts were prepared by modifying Keggin POM H4PMo11VO40 with a coumarin-surfactant through electrostatic interactions. The results indicate that (Coumarin)3HPMo11VO40 exhibits excellent catalytic activity in the selective oxidation of benzyl alcohol using air as the oxidant, where the conversion of benzyl alcohol is 99%, and the selectivity for benzaldehyde is 100%. The excellent catalytic performance can be attributed to π-π* conjugate effects with the reactant, and the structural characteristics of the large BET specific surface area and pore size of the catalyst.

AB - Two novel polyoxometalate-based catalysts were prepared by modifying Keggin POM H4PMo11VO40 with a coumarin-surfactant through electrostatic interactions. The results indicate that (Coumarin)3HPMo11VO40 exhibits excellent catalytic activity in the selective oxidation of benzyl alcohol using air as the oxidant, where the conversion of benzyl alcohol is 99%, and the selectivity for benzaldehyde is 100%. The excellent catalytic performance can be attributed to π-π* conjugate effects with the reactant, and the structural characteristics of the large BET specific surface area and pore size of the catalyst.

KW - Benzaldehyde (BzH)

KW - Benzyl alcohol (BzOH)

KW - Coumarin-surfactant

KW - Polyoxometalate (POM)

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