Chlorine randomization between phenyl groups in the electron impact-induced fragmentation of polychlorinated biphenyls

S. Safe, O. Hutzinger

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

The mass spectra of dichlorobiphenyls show chlorine randomization over both phenyl rings with the exception of 2,2′- and 2,6-biphenyl (I, e and f) in which both chlorine atoms are ortho to the Ph-Ph bond; similar results are obtained with tetrachlorobiphenyls which show chlorine randomization in the M - Cl2 ion.

Original languageEnglish (US)
Pages (from-to)446-448
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
StatePublished - 1971

ASJC Scopus subject areas

  • Molecular Medicine

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