Characterization of actinide metallofullerenes

K. Akiyama; K. Sueki; Y. L. Zhao; H. Haba; K. Tsukada; T. Kodama; K. Kikuchi; T. Ohtsuki; Y. Nagame; H. Nakahara; M. Katada

doi:10.1063/1.1420146

Characterization of actinide metallofullerenes

K. Akiyama, K. Sueki, Y. L. Zhao, H. Haba, K. Tsukada, T. Kodama, K. Kikuchi, T. Ohtsuki, Y. Nagame, H. Nakahara, M. Katada

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

10 Scopus citations

Abstract

In this paper, the characterization of a number of actinoid metallofullerenes is reported. From the similarity of the HPLC elution behavior and identification by mass spectroscopy we observe that the electronic structures of U, Np, and Am metallofullerenes are extremely similar to that of Ce@C₈₂ and that the oxidation states of encapsulated Th and Pa have the value +3 or 4.

Original language	English (US)
Title of host publication	Nanonetwork Materials
Subtitle of host publication	Fullerenes, Nanotubes, and Related Systems
Editors	Tsuneya Ando, Yoshihiro Iwasawa, Koichi Kikuchi, Yahachi Saito, Susumu Saito, Mototada Kobayashi
Publisher	American Institute of Physics Inc.
Pages	437-440
Number of pages	4
ISBN (Electronic)	0735400326, 9780735400320
DOIs	https://doi.org/10.1063/1.1420146
State	Published - Oct 16 2001
Event	International Symposium on Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems 2001 - Kamakura, Japan Duration: Jan 15 2001 → Jan 18 2001

Publication series

Name	AIP Conference Proceedings
Volume	590
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Other

Other	International Symposium on Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems 2001
Country	Japan
City	Kamakura
Period	1/15/01 → 1/18/01

ASJC Scopus subject areas

Physics and Astronomy(all)

Access to Document

10.1063/1.1420146

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Akiyama, K., Sueki, K., Zhao, Y. L., Haba, H., Tsukada, K., Kodama, T., Kikuchi, K., Ohtsuki, T., Nagame, Y., Nakahara, H., & Katada, M. (2001). Characterization of actinide metallofullerenes. In T. Ando, Y. Iwasawa, K. Kikuchi, Y. Saito, S. Saito, & M. Kobayashi (Eds.), Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems (pp. 437-440). (AIP Conference Proceedings; Vol. 590). American Institute of Physics Inc.. https://doi.org/10.1063/1.1420146

Characterization of actinide metallofullerenes. / Akiyama, K.; Sueki, K.; Zhao, Y. L.; Haba, H.; Tsukada, K.; Kodama, T.; Kikuchi, K.; Ohtsuki, T.; Nagame, Y.; Nakahara, H.; Katada, M.

Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems. ed. / Tsuneya Ando; Yoshihiro Iwasawa; Koichi Kikuchi; Yahachi Saito; Susumu Saito; Mototada Kobayashi. American Institute of Physics Inc., 2001. p. 437-440 (AIP Conference Proceedings; Vol. 590).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Akiyama, K, Sueki, K, Zhao, YL, Haba, H, Tsukada, K, Kodama, T, Kikuchi, K, Ohtsuki, T, Nagame, Y, Nakahara, H & Katada, M 2001, Characterization of actinide metallofullerenes. in T Ando, Y Iwasawa, K Kikuchi, Y Saito, S Saito & M Kobayashi (eds), Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems. AIP Conference Proceedings, vol. 590, American Institute of Physics Inc., pp. 437-440, International Symposium on Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems 2001, Kamakura, Japan, 1/15/01. https://doi.org/10.1063/1.1420146

Akiyama, K. ; Sueki, K. ; Zhao, Y. L. ; Haba, H. ; Tsukada, K. ; Kodama, T. ; Kikuchi, K. ; Ohtsuki, T. ; Nagame, Y. ; Nakahara, H. ; Katada, M. / Characterization of actinide metallofullerenes. Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems. editor / Tsuneya Ando ; Yoshihiro Iwasawa ; Koichi Kikuchi ; Yahachi Saito ; Susumu Saito ; Mototada Kobayashi. American Institute of Physics Inc., 2001. pp. 437-440 (AIP Conference Proceedings).

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AU - Kodama, T.

AU - Kikuchi, K.

AU - Ohtsuki, T.

AU - Nagame, Y.

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AU - Katada, M.

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AB - In this paper, the characterization of a number of actinoid metallofullerenes is reported. From the similarity of the HPLC elution behavior and identification by mass spectroscopy we observe that the electronic structures of U, Np, and Am metallofullerenes are extremely similar to that of Ce@C82 and that the oxidation states of encapsulated Th and Pa have the value +3 or 4.

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