Cerium(III) chloride-mediated vinylation of acylsilanes: A convenient new entry to silylated allylic alcohols

B. F. Bonini, M. Comes-Franchini, M. Fochi, G. Mazzanti, A. Ricci, Greta Varchi

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

The reaction of alkyl, cycloalkyl, aromatic, heteroaromatic and α,β-unsaturated acylsilanes 1-7 and of homochiral acylsilanes 15 and 16 with the complex vinylmagnesium bromide/CeCl3 affords the silylated allylic alcohols in satisfactory to excellent yields.

Original languageEnglish (US)
Pages (from-to)1688-1690
Number of pages3
JournalSynlett
Issue number11
StatePublished - Dec 4 2000

Keywords

  • Acylsilanes
  • Cerium chloride
  • Diastereoselectivity
  • Silylated allylic alcohols
  • Vinylation

ASJC Scopus subject areas

  • Organic Chemistry

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