Calix[3]carbazole: A C3-symmetrical receptor for barium ion

Zhaozheng Yang; Zhangmin Tian; Peng Yang; Tuo Deng; Gang Li; Xue Zhou; Yan Chen; Liang Zhao; Hongyan Shen

doi:10.1016/j.saa.2016.11.013

Calix[3]carbazole: A C₃-symmetrical receptor for barium ion

Zhaozheng Yang, Zhangmin Tian, Peng Yang, Tuo Deng, Gang Li, Xue Zhou, Yan Chen, Liang Zhao, Hongyan Shen

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The binding ability of calix[3]carbazole (1) to metal ions has been investigated. It is found that 1 could serve as a non crown ether based, C₃-symmetrical receptor for Ba^{2 +} via the marriage of cation–π and cation–dipole interactions. FID assay further illustrates that 1 could selectively interact with Ba^{2 +} over Pd^{2 +}. A possible binding mechanism for [1-Ba^{2 +}] complex is proposed.

Original language	English (US)
Pages (from-to)	32-36
Number of pages	5
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	174
DOIs	https://doi.org/10.1016/j.saa.2016.11.013
State	Published - Mar 5 2017

Keywords

Barium ion
C-symmetrical
Carbazole
FID
Receptor

ASJC Scopus subject areas

Analytical Chemistry
Atomic and Molecular Physics, and Optics
Instrumentation
Spectroscopy

Access to Document

10.1016/j.saa.2016.11.013

Cite this

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title = "Calix[3]carbazole: A C3-symmetrical receptor for barium ion",

abstract = "The binding ability of calix[3]carbazole (1) to metal ions has been investigated. It is found that 1 could serve as a non crown ether based, C3-symmetrical receptor for Ba2 + via the marriage of cation–π and cation–dipole interactions. FID assay further illustrates that 1 could selectively interact with Ba2 + over Pd2 +. A possible binding mechanism for [1-Ba2 +] complex is proposed.",

keywords = "Barium ion, C-symmetrical, Carbazole, FID, Receptor",

author = "Zhaozheng Yang and Zhangmin Tian and Peng Yang and Tuo Deng and Gang Li and Xue Zhou and Yan Chen and Liang Zhao and Hongyan Shen",

note = "Funding Information: This work was supported by the National Natural Science Foundation of China (Grant 21102095 ), Liaoning Provincial Natural Science Foundation (Grant 2015020752 ) and by programs for the innovative research team of the Ministry of Education and for the Liaoning innovative research team in university. Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

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doi = "10.1016/j.saa.2016.11.013",

language = "English (US)",

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journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

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T1 - Calix[3]carbazole

T2 - A C3-symmetrical receptor for barium ion

AU - Yang, Zhaozheng

AU - Tian, Zhangmin

AU - Yang, Peng

AU - Deng, Tuo

AU - Li, Gang

AU - Zhou, Xue

AU - Chen, Yan

AU - Zhao, Liang

AU - Shen, Hongyan

N1 - Funding Information: This work was supported by the National Natural Science Foundation of China (Grant 21102095 ), Liaoning Provincial Natural Science Foundation (Grant 2015020752 ) and by programs for the innovative research team of the Ministry of Education and for the Liaoning innovative research team in university. Publisher Copyright: © 2016 Elsevier B.V.

PY - 2017/3/5

Y1 - 2017/3/5

N2 - The binding ability of calix[3]carbazole (1) to metal ions has been investigated. It is found that 1 could serve as a non crown ether based, C3-symmetrical receptor for Ba2 + via the marriage of cation–π and cation–dipole interactions. FID assay further illustrates that 1 could selectively interact with Ba2 + over Pd2 +. A possible binding mechanism for [1-Ba2 +] complex is proposed.

AB - The binding ability of calix[3]carbazole (1) to metal ions has been investigated. It is found that 1 could serve as a non crown ether based, C3-symmetrical receptor for Ba2 + via the marriage of cation–π and cation–dipole interactions. FID assay further illustrates that 1 could selectively interact with Ba2 + over Pd2 +. A possible binding mechanism for [1-Ba2 +] complex is proposed.

KW - Barium ion

KW - C-symmetrical

KW - Carbazole

KW - FID

KW - Receptor

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