Abstract
The uniform and non-uniform scaling properties of the exact correlation energy functional are applied in the study of rational, polynomial, logarithmic and exponential local and gradient-dependent forms of the correlation energy functional, which depend separably on the density and on the reduced variable of the gradient of the density. No local or gradient-dependent polynomial, rational, logarithmic, and exponential form can satisfy all the properties at the same time for the high- or low-density limits. A slight violation of some of the conditions may lead to simple approximate expressions for the correlation energy functional.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 371-376 |
| Number of pages | 6 |
| Journal | Chemical Physics Letters |
| Volume | 322 |
| Issue number | 5 |
| DOIs | |
| State | Published - May 26 2000 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry
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