5p Electronic properties of Gd in Gd@C82(OH)x studied by synchrotron radiation XPS

Jun Tang, Gengmei Xing, Hui Yuan, Xingfa Gao, Long Jing, Shukuan Wang, Yue Cheng, Yuliang Zhao

Research output: Contribution to journalArticle

10 Scopus citations

Abstract

The electronic properties of the metal atoms encaged in a fullerence cage were investigated using synchrotron X-ray photoelectron spectroscopy. Systematic variations in photoemission of valence band of Gd@C82, Gd@C 82(OH)12, and Gd@C82(OH)22 were observed in Gd 5p levels. The results suggest that the electronic properties of the inner metal atom can be efficiently modulated by surface chemistry of the fullerene cage.

Original languageEnglish (US)
Pages (from-to)307-310
Number of pages4
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume272
Issue number2
DOIs
StatePublished - May 2007

ASJC Scopus subject areas

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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